Product ID:PHOTAFIX 224 FIXER/REPLENISHER, 28031
MSDS Date:04/18/1991
FSC:6750
NIIN:00N079054
MSDS Number: CGYWH

ALLIED PHOTO PRODUCTS CO INC

5440 A OAKBROOK PKWY
NORCROSS, GA 30093
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 404-448-0250

Cage: 1CG79

ALLIED PHOTO PRODUCT CO,SUB OF ALLIED PRODUCT CORP

NORCROSS, GA 30093-2251 US

Telephone: 770-448-0250

Cage: 1CG79

THIOSULFURIC ACID, DIAMMONIUM SALT; (AMMONIUM THIOSULFATE)

CAS: 7783-18-8

RTECS: XN6465000

Fraction By Weight: 15-20%

OSHA PEL N/K

ACGIH TLV: N/K

SODIUM SULFITE

CAS: 7757-83-7

RTECS: WE2150000

Fraction By Weight: 1-5%

OSHA PEL N/K

ACGIH TLV: N/K

ACETIC ACID (CERCLA)

CAS: 64-19-7

RTECS: AF1225000

Fraction By Weight: 1-5%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM/15 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 55-60%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: LOW HAZARD FOR
ORDINARY INDUSTRIAL HANDLING. EYES: CONTACT MAY CAUSE IRRITATION.
SKIN: REPEATED AND PROLONGED CONTACT MAY CAUSE IRRITATION.
INGESTION: DO NOT TAKE INTERNALLY. MAY BE HARMFUL IF SWALLOWED.
CHRONIC: NONE SPECIFIED BY MANUFACTURER.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. SEEK MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. IF
IRRITATION OCCURS, SEEK MEDICAL ATTENTION. INGESTION: INDUCE
VOMITING. SEEK MEDICAL ATTENTION IMMEDIATELY GIVING FULL DETAILS
OF AMOUNT INGESTED AND TOXICITY. INHALATION: MOVE TO FRESH AIR.

Flash Point:NONE
Extinguishing Media:USE METHOD APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:WHEN HEATED TO DECOMPOSITION, IT CAN EMIT
TOXIC FUMES OF SO*X AND AMMONIA.

Spill Release Procedures:WEAR PROTECTIVE CLOTHING AS SPECIFIED.
NEUTRALIZE WITH SODIUM BICARBONATE. IF FEDERAL, STATE AND LOCAL
LAWS PERMIT, FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
Neutralizing Agent:SODIUM BICARBONATE.

Handling and Storage Precautions:DO NOT STORE OR CONSUME FOOD, DRINK OR
TOBACCO IN SURROUNDING AREA.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:SHOULD NOT BE NECESSARY UNDER NORMAL CONDITIONS.
IF EXPOSED TO VAPORS THAT EXCEED TLV OR PEL, WEAR A NIOSH APPROVED
VAPOR RESPIRATOR.
Ventilation:GOOD LOCAL MECHANICAL VENTILATION SHOULD BE SUFFICIENT.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . WEAR PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE.
Supplemental Safety and Health
WASTE DISP METH: AGENCIES TO ASCERTAIN PROPER DISP PROCEDURES.

Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:17.0
Vapor Density:0.6
Spec Gravity:1.33
pH:4.6
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, SLIGHT VINEGAR ODOR
Percent Volatiles by Volume:65(WT)

Stability Indicator/Materials to Avoid:YES
MINERAL ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION, IT CAN
EMIT TOXIC FUMES OF SO*2, CARBON DIOXIDE AND POSSIBLY CARBON
MONOXIDE.

Waste Disposal Methods:NEUT W/SODIUM BICARBONATE. IF FED, STATE &/LOC
LAWS PERMIT, FLUSH TO SEWER W/LGE AMTS OF WATER. OTHERWISE DISP OF
CONTAM PROD & MATLS USED IN CLEANING UP SPILL IN A MANNER APPRVD
FOR THIS MATL. CONSUL T PROPER FED, STATE &/LOC REGULATORY (SUP
DAT)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.